Let's say we have an acid (HA) and its conjugate base (A-) in a solution. The chemical formula is written as the following:
The buffer equation (Henderson-Hasselbalch equation) is derived for the above acid-conjugate base pair as shown by the following equations:
The last equation is the buffer equation (Henderson-Hasselbalch equation) that is used for buffer calculation of an acid - conjugate base pair.
If we have a base (B) and its conjugate acid (BH+) then the chemical formula is:
B + H2O ↔ BH+ + OH-
and the derivation is the following:
The last equation in the above is the buffer equation for a base-conjugate acid pair. Note that in the above derivation we used the relation pKw = pH + pOH.
HA + H2O ↔ H3O+ + A-
The buffer equation (Henderson-Hasselbalch equation) is derived for the above acid-conjugate base pair as shown by the following equations:
The last equation is the buffer equation (Henderson-Hasselbalch equation) that is used for buffer calculation of an acid - conjugate base pair.
If we have a base (B) and its conjugate acid (BH+) then the chemical formula is:
B + H2O ↔ BH+ + OH-
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